Download Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis Ebook PDF

Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis

Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis
A Book

by S. Ted Oyama

  • Publisher : Elsevier
  • Release : 2011-10-13
  • Pages : 528
  • ISBN : 9780080558011
  • Language : En, Es, Fr & De
GET BOOK

The catalytic epoxidation of olefins plays an important role in the industrial production of several commodity compounds, as well as in the synthesis of many intermediates, fine chemicals, and pharmaceuticals. The scale of production ranges from millions of tons per year to a few grams per year. The diversity of catalysts is large and encompasses all the known categories of catalyst type: homogeneous, heterogeneous, and biological. This book summarizes the current status in these fields concentrating on rates, kinetics, and reaction mechanisms, but also covers broad topics including modeling, computational simulation, process concepts, spectroscopy and new catalyst development. The similarities and distinctions between the different reaction systems are compared, and the latest advances are described. * Comprehensive listing of epoxide products * Broad comparison of turnover frequencies of homogeneous, hetergeneous, main-group, biomimetic and biological catalysts * Analysis of the general strengths and weaknesses of varied catalytic systems * Detailed description of the mechanisms of reaction for classical and emerging catalysts

Homogeneous Catalysis

Homogeneous Catalysis
Mechanisms and Industrial Applications

by Sumit Bhaduri,Doble Mukesh

  • Publisher : John Wiley & Sons
  • Release : 2014-09-11
  • Pages : 288
  • ISBN : 1118872517
  • Language : En, Es, Fr & De
GET BOOK

Over the last decade, the area of homogeneous catalysis withtransition metal has grown in great scientific interest andtechnological promise, with research in this area earning threeNobel Prizes and filing thousands of patents relating tometallocene and non-metallocene single site catalysts, asymmetriccatalysis, carbon-carbon bond forming metathesis and cross couplingreactions. This text explains these new developments in a unified, cogent, andcomprehensible manner while also detailing earlier discoveries andthe fundamentals of homogeneous catalysis. Serving as a self-studyguide for students and all chemists seeking to gain entry into thisfield, it can also be used by experienced researchers from bothacademia and industry for referring to leading state of the artreview articles and patents, and also as a quick self-study manualin an area that is outside their immediate expertise. The bookfeatures: • Topics including renewable feed stocks (biofuel,glycerol), carbon dioxide based processes (polycarbonates),fluorous solvents, ionic liquid, hydroformylation, polymerization,oxidation, asymmetric catalysis, and more • Basic principles of organometallic chemistry,homogeneous catalysis, and relevant technological issues • Problems and answers, industrial applications (casestudies), and examples from proven industrial processes with cleardiscussions on environmental and techno-commercial issues • Extensive references to cutting edge research withapplication potential and leading patents • Tables and illustrations to help explain difficultconcepts

Development of Homogeneous and Heterogeneous Epoxidation Catalysts Using Simple Mn(II) [superscript] Complexes and Peracetic Acid

Development of Homogeneous and Heterogeneous Epoxidation Catalysts Using Simple Mn(II) [superscript] Complexes and Peracetic Acid
A Book

by Andrew J. Murphy

  • Publisher : Unknown Publisher
  • Release : 2005
  • Pages : 208
  • ISBN : 9876543210XXX
  • Language : En, Es, Fr & De
GET BOOK

Heterogeneous Catalysis in Organic Chemistry

Heterogeneous Catalysis in Organic Chemistry
A Book

by Gerard V. Smith,Ferenc Notheisz

  • Publisher : Academic Press
  • Release : 1999-06-30
  • Pages : 346
  • ISBN : 9780080524801
  • Language : En, Es, Fr & De
GET BOOK

The features of this book which will be of special interest to academic organic chemists are the introduction (Chapter 1), which presents a short course on the concepts and language of heterogeneous catalysis, covers organic reaction mechanisms of hydrogenation (Chapter 2), hydrogenolysis (Chapter 4), and oxidation (Chapter 6), a presents problems and solutions specific for running heterogeneous catalytic organic reactions in solution. These materials can supplement advanced chemistry courses. Most synthetic organic chemists use a variety of "protecting groups" which they attach to functional groups (reactive groups of atoms) while some reaction is being conducted on another part of the molecule. These protecting groups prevent reactions of the functional groups during other reactions and are removed later by a heterogeneous catalytic method called hydrogenolysis. One unique feature of this book, not found in other books on catalysis, is an exhaustive chapter (Chapter 4) on hydrogenolysis, which is dredged from the recent synthetic literature published by modern organic chemists. Academic organic chemists should find this chapter extremely useful and may wish to adopt the book as a supplement for advanced organic chemistry courses designed for seniors and for graduate students. It will also be useful for professors and their research groups engaged in synthetic organic chemistry. Many academic organic chemists are not aware of recent advances in heterogeneous enantioselective catalysis (Chapter 3) or in selective low temperature, liquid phase heterogeneous catalytic oxidations by hydrogen peroxide (Chapter 6). These specialty topics are timely and may be new to academic organic chemists and can be used to supplement their advanced courses. Several features of this book will also be of special interest to industrial chemists who are unfamiliar with heterogeneous catalysis. Many good organic chemists are hire by industry. They synthesize a new compound using standard organic synthetic techniques but are informed by their supervisor that they must convert some of their synthetic steps into heterogeneous catalytic steps. They may not have been exposed to heterogeneous catalysis and have few places to turn. This book offers them a crash course in heterogeneous catalysis as well as many examples of reactions and conditions with which they can start their search. Those industrial organic chemists already familiar with heterogeneous catalysis will find this book useful as a reference to many examples in the recent literature. They will find recent surface science discoveries correlated with heterogeneous catalysis or organic reactions and mechanistic suggestions designed to stimulate innovative nontraditional thinking about organic reactions on surfaces. Written by organic chemists for organic chemists Introduces heterogeneous catalysis concepts and language Presents a comprehensive compilation of protecting group removal procedures Covers liquid-phase hydrogenations, hydrogenolysis, and oxidations Addresses heterogeneous methods for producing pure enantiomers of chiral products Examines the emerging field of heterogenized homogeneous catalysts Mixes practical applications with mechanistic interpretations

Fine Chemicals through Heterogeneous Catalysis

Fine Chemicals through Heterogeneous Catalysis
A Book

by R. A. Sheldon,Herman van Bekkum

  • Publisher : John Wiley & Sons
  • Release : 2008-07-11
  • Pages : 636
  • ISBN : 3527612971
  • Language : En, Es, Fr & De
GET BOOK

Nowadays, the chemical industry is under increased pressure to develop cleaner production processes and technologies. Much effort is devoted to the development of heterogeneous catalysts and their application in industrial-scale organic synthesis. This handbook concentrates on current attempts, focusing on fine chemical production. With contributions from an impressive array of international experts, this is essential reading for everyone interested in the advances in this field.

Applied Homogeneous Catalysis

Applied Homogeneous Catalysis
A Book

by Arno Behr,Peter Neubert

  • Publisher : John Wiley & Sons
  • Release : 2012-04-16
  • Pages : 688
  • ISBN : 3527326413
  • Language : En, Es, Fr & De
GET BOOK

Adopting a didactic approach at an advanced, masters level, this concise textbook provides an array of questions & answers and features numerous industrial case studies and examples, with references for further, more detailed reading and to the latest peer-reviewed articles at the end of each chapter. A significant feature is the book’s treatment of more recently developed catalytic processes and their applications in the pharmaceutical and fi ne chemical industries, with an indication of their present and future commercial impact. Written by a dedicated lecturer with a wealth of experience in industry, this is an invaluable tool for practicing chemical engineers and chemists who need to advance their education in this vibrant and expanding field.

Liquid Phase Aerobic Oxidation Catalysis

Liquid Phase Aerobic Oxidation Catalysis
Industrial Applications and Academic Perspectives

by Shannon S. Stahl,Paul L. Alsters

  • Publisher : John Wiley & Sons
  • Release : 2016-07-13
  • Pages : 456
  • ISBN : 3527690158
  • Language : En, Es, Fr & De
GET BOOK

The first book to place recent academic developments within the context of real life industrial applications, this is a timely overview of the field of aerobic oxidation reactions in the liquid phase that also illuminates the key challenges that lie ahead. As such, it covers both homogeneous as well as heterogeneous chemocatalysis and biocatalysis, along with examples taken from various industries: bulk chemicals and monomers, specialty chemicals, flavors and fragrances, vitamins, and pharmaceuticals. One chapter is devoted to reactor concepts and engineering aspects of these methods, while another deals with the relevance of aerobic oxidation catalysis for the conversion of renewable feedstock. With chapters written by a team of academic and industrial researchers, this is a valuable reference for synthetic and catalytic chemists at universities as well as those working in the pharmaceutical and fine chemical industries seeking a better understanding of these reactions and how to design large scale processes based on this technology.

Iron Catalysis: Design And Applications

Iron Catalysis: Design And Applications
A Book

by Jose M Palomo

  • Publisher : World Scientific
  • Release : 2021-03-15
  • Pages : 352
  • ISBN : 1786349639
  • Language : En, Es, Fr & De
GET BOOK

Iron Catalysis: Design and Applications is an exciting new book that takes readers inside the world of iron catalysis guided by international catalysis expert, Dr Jose M Palomo. Iron is the most abundant metal in the planet, cost-effective, environmentally friendly, with an easily manipulated remediation process. In the last few years the use of this nonprecious metal has gained extraordinary attention particularly for its potential as a catalyst in different areas. This book compiles a series of chapters describing the most significant advances in the last few years since the design of different iron catalysts and nanocatalysts and iron-containing artificial and natural enzymes. The chapters also cover its application in different areas of interest such as organic synthesis, environmental remediation, enzyme-like activities or the creation of novel types of electrodes for battery design.

Computational Methods in Organometallic Catalysis

Computational Methods in Organometallic Catalysis
From Elementary Reactions to Mechanisms

by Yu Lan

  • Publisher : John Wiley & Sons
  • Release : 2021-03-24
  • Pages : 672
  • ISBN : 3527346058
  • Language : En, Es, Fr & De
GET BOOK

The book includes a historical introduction to organometallic chemistry, a survey of mechanisms, and an extensive introduction to quantum mechanical computational methods.

Nanotechnology in Catalysis

Nanotechnology in Catalysis
Applications in the Chemical Industry, Energy Development, and Environment Protection

by Bert Sels,Marcel Van de Voorde

  • Publisher : John Wiley & Sons
  • Release : 2017-06-20
  • Pages : 1500
  • ISBN : 352769983X
  • Language : En, Es, Fr & De
GET BOOK

Reflecting the R&D efforts in the field that have resulted in a plethora of novel applications over the past decade, this handbook gives a comprehensive overview of the tangible benefits of nanotechnology in catalysis. By bridging fundamental research and industrial development, it provides a unique perspective on this scientifically and economically important field. While the first three parts are devoted to preparation and characterization of nanocatalysts, the final three provide in-depth insights into their applications in the fine chemicals industry, the energy industry, and for environmental protection, with expert authors reporting on real-life applications that are on the brink of commercialization. Timely reading for catalytic chemists, materials scientists, chemists in industry, and process engineers.

Modern Heterogeneous Catalysis

Modern Heterogeneous Catalysis
An Introduction

by Rutger A. van Santen

  • Publisher : John Wiley & Sons
  • Release : 2017-02-15
  • Pages : 190
  • ISBN : 3527694528
  • Language : En, Es, Fr & De
GET BOOK

Written by one of the world's leading experts on the topic, this advanced textbook is the perfect introduction for newcomers to this exciting field. Concise and clear, the text focuses on such key aspects as kinetics, reaction mechanism and surface reactivity, concentrating on the essentials. The author also covers various catalytic systems, catalysis by design, and activation-deactivation. A website with supplementary material offers additional figures, original material and references.

Liquid Phase Oxidation via Heterogeneous Catalysis

Liquid Phase Oxidation via Heterogeneous Catalysis
Organic Synthesis and Industrial Applications

by Mario G. Clerici,Oxana A. Kholdeeva

  • Publisher : John Wiley & Sons
  • Release : 2013-04-26
  • Pages : 546
  • ISBN : 1118356756
  • Language : En, Es, Fr & De
GET BOOK

Sets the stage for environmentally friendly industrialorganic syntheses From basic principles to new and emerging industrialapplications, this book offers comprehensive coverage ofheterogeneous liquid-phase selective oxidation catalysis. It fullyexamines the synthesis, characterization, and application ofcatalytic materials for environmentally friendly organic syntheses.Readers will find coverage of all the important classes ofcatalysts, with an emphasis on their stability and reusability. Liquid Phase Oxidation via Heterogeneous Catalysisfeatures contributions from an international team of leadingchemists representing both industry and academia. The book beginswith a chapter on environmentally benign oxidants and thencovers: Selective oxidations catalyzed by TS-1 and othermetal-substituted zeolites Selective catalytic oxidation over ordered nanoporousmetallo-aluminophosphates Selective oxidations catalyzed by mesoporousmetal-silicates Liquid phase oxidation of organic compounds by supportedmetal-based catalysts Selective liquid phase oxidations in the presence of supportedpolyoxometalates Selective oxidations catalyzed by supported metalcomplexes Liquid phase oxidation of organic compounds by metal-organicframeworks Heterogeneous photocatalysis for selective oxidations withmolecular oxygen All the chapters dedicated to specific types of catalysts followa similar organization and structure, making it easy to compare theadvantages and disadvantages of different catalysts. The finalchapter examines the latest industrial applications, such as theproduction of catechol and hydroquinone, cyclohexanone oxime, andpropylene oxide. With its unique focus on liquid phase heterogeneous oxidationcatalysis, this book enables researchers in organic synthesis andoxidation catalysis to explore and develop promising new catalyticmaterials and synthetic routes for a broad range of industrialapplications.

Advances in Catalysis

Advances in Catalysis
A Book

by Anonim

  • Publisher : Academic Press
  • Release : 2014-11-24
  • Pages : 434
  • ISBN : 0128003006
  • Language : En, Es, Fr & De
GET BOOK

Advances in Catalysis fills the gap between the journal papers and the textbooks across the diverse areas of catalysis research. For more than 60 years Advances in Catalysis has been dedicated to recording progress in the field of catalysis and providing the scientific community with comprehensive and authoritative reviews. This series is invaluable to chemical engineers and chemists working in the field of catalysis in academia or industry. Authoritative reviews written by experts in the field Topics selected to reflect progress of the field Insightful and critical articles, fully edited to suit various backgrounds

Catalysis for Clean Energy and Environmental Sustainability

Catalysis for Clean Energy and Environmental Sustainability
Petrochemicals and Refining Processes - Volume 2

by K. K. Pant

  • Publisher : Springer Nature
  • Release : 2021
  • Pages : 329
  • ISBN : 3030650219
  • Language : En, Es, Fr & De
GET BOOK

Ion Exchange and Solvent Extraction

Ion Exchange and Solvent Extraction
A Series of Advances, Volume 22

by Arup K. Sengupta

  • Publisher : CRC Press
  • Release : 2017-07-12
  • Pages : 248
  • ISBN : 1315350637
  • Language : En, Es, Fr & De
GET BOOK

Since the Second World War, the field of ion exchange has taken a dominant role in offering solutions to many problems in the developed and developing world. It has evolved to a wide array of applications, including mining, microelectronics, drug delivery and detection, food, fertilizers, chemical cleaning, catalysis, bioseparation, water management, environmental research and practices, and energy. The six chapters in this book represent diverse contributions from researchers around the globe who are making noticeable strides in the field in currently important areas: Brackish water desalination Removing boron from water Sustainable approaches for synthesizing commercially important epoxide building blocks Solid-phase heavy-metal separation Separating concentrated ion mixtures in sorption columns Sensing toxic metals Ion Exchange and Solvent Extraction: A Series of Advances, Volume 22 provides a focused review of new materials and new processes that have developed and are rapidly growing. It describes cutting-edge research and practices in the use of ion exchange for building a cleaner, sustainable world and provides thoughtful insights on what ion exchange may do for us in the future.

Modern Heterocyclic Chemistry

Modern Heterocyclic Chemistry
Vol. 1

by Julio Alvarez-Builla,Juan José Vaquero,José Barluenga

  • Publisher : John Wiley & Sons
  • Release : 2011
  • Pages : 633
  • ISBN : 3527332014
  • Language : En, Es, Fr & De
GET BOOK

Aspects of Homogeneous Catalysis

Aspects of Homogeneous Catalysis
A Book

by R. Ugo

  • Publisher : Springer Science & Business Media
  • Release : 2012-12-06
  • Pages : 212
  • ISBN : 9400983719
  • Language : En, Es, Fr & De
GET BOOK

Sustainable Inorganic Chemistry

Sustainable Inorganic Chemistry
A Book

by David A. Atwood

  • Publisher : John Wiley & Sons
  • Release : 2016-10-17
  • Pages : 576
  • ISBN : 1118703421
  • Language : En, Es, Fr & De
GET BOOK

The Earth's natural resources are finite and easily compromised by contamination from industrial chemicals and byproducts from the degradation of consumer products. The growing field of green and sustainable chemistry seeks to address this through the development of products and processes that are environmentally benign while remaining economically viable. Inorganic chemistry plays a critical role in this endeavor in areas such as resource extraction and isolation, renewable energy, catalytic processes, waste minimization and avoidance, and renewable industrial feedstocks. Sustainable Inorganic Chemistry presents a comprehensive overview of the many new developments taking place in this rapidly expanding field, in articles that discuss fundamental concepts alongside cutting-edge developments and applications. The volume includes educational reviews from leading scientists on a broad range of topics including: inorganic resources, sustainable synthetic methods, alternative reaction conditions, heterogeneous catalysis, photocatalysis, sustainable nanomaterials, renewable and clean fuels, water treatment and remediation, waste valorization and life cycle sustainability assessment. The content from this book will be added online to the Encyclopedia of Inorganic and Bioinorganic Chemistry.

Catalysis

Catalysis
Volume 28

by James J. Spivey,Yi-Fan Han,K. M. Dooley

  • Publisher : Royal Society of Chemistry
  • Release : 2016-02-22
  • Pages : 294
  • ISBN : 1782624279
  • Language : En, Es, Fr & De
GET BOOK

Industrial and academic scientists face increasing challenges to find cost-effective and environmentally sound catalysts for a variety of applications. This volume provides a balanced and in-depth review of the modern approaches to some of these challenges covering major areas such as catalysts for green catalytic processes, research and development of hydrocracking catalysts, using nanoclusters as catalysts and preparation of foams.

Polyoxomolybdates as Green Catalysts for Aerobic Oxidation

Polyoxomolybdates as Green Catalysts for Aerobic Oxidation
A Book

by Anjali Patel,Soyeb Pathan

  • Publisher : Springer
  • Release : 2014-11-22
  • Pages : 55
  • ISBN : 3319129880
  • Language : En, Es, Fr & De
GET BOOK

Heterogeneously catalyzed selective oxidations of alcohols is a highly topical field. The first chapter of this brief describes the importance of the selective oxidation of alcohols and advantages of heterogeneous catalysts over conventional catalysts, use of environmentally benign oxidants, and the design of selective catalysts by tailoring of polyoxometalates at the molecular level. Chapter 2 describes synthesis, characterization 11-molybdophosphate based supported materials and their use as heterogeneous catalysts for oxidation of alcohols with molecular oxygen under solvent free mild reaction condition. ZrO2, Al2O3, MCM-41 and zeolite Hβ were used as supports. Chapter 3 describes synthesis, characterization of transition metals (Mn, Co, Ni, Cu)- substituted phosphomolybdates and their use as heterogeneous catalysts for oxidation of alcohols with molecular oxygen under solvent free mild reaction condition. Chapter 4 describes conclusive remarks for present catalytic systems.