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Metal Nanoclusters in Catalysis and Materials Science: The Issue of Size Control

Metal Nanoclusters in Catalysis and Materials Science: The Issue of Size Control
A Book

by Benedetto Corain,Guenter Schmid,N Toshima

  • Publisher : Elsevier
  • Release : 2011-08-11
  • Pages : 470
  • ISBN : 9780080555003
  • Language : En, Es, Fr & De
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Metal Nanoclusters in Catalysis and Materials Science: The Issue of Size Control deals with the synthesis of metal nanoclusters along all known methodologies. Physical and chemical properties of metal nanoclusters relevant to their applications in chemical processing and materials science are covered thoroughly. Special attention is given to the role of metal nanoclusters size and shape in catalytic processes and catalytic applications relevant to industrial chemical processing. An excellent text for expanding the knowledge on the chemistry and physics of metal nanoclusters. Divided in two parts; Part I deals with general aspects of the matter and Part II has to be considered a useful handbook dealing with the production of metal nanoclusters, especially from their size-control point of view. * Divided into two parts for ease of reference: general and operational * Separation of synthetic aspects, physical properties and applications * Specific attention is given to the task of metal nanoclusters size-control

Nanoparticles in Catalysis

Nanoparticles in Catalysis
Advances in Synthesis and Applications

by Karine Philippot,Alain Roucoux

  • Publisher : John Wiley & Sons
  • Release : 2021-04-29
  • Pages : 384
  • ISBN : 3527821759
  • Language : En, Es, Fr & De
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Nanoparticles in Catalysis Discover an essential overview of recent advances and trends in nanoparticle catalysis Catalysis in the presence of metal nanoparticles is an important and rapidly developing research field at the frontier of homogeneous and heterogeneous catalysis. In Nanoparticles in Catalysis, accomplished chemists and authors Karine Philippot and Alain Roucoux deliver a comprehensive guide to the key aspects of nanoparticle catalysis, ranging from synthesis, activation methodology, characterization, and theoretical modeling, to application in important catalytic reactions, like hydrogen production and biomass conversion. The book offers readers a review of modern and efficient tools for the synthesis of nanoparticles in solution or onto supports. It emphasizes the application of metal nanoparticles in important catalytic reactions and includes chapters on activation methodology and supported nanoclusters. Written by an international team of leading voices in the field, Nanoparticles in Catalysis is an indispensable resource for researchers and professionals in academia and industry alike. Readers will also benefit from the inclusion of: A thorough introduction to New Trends in the Design of Metal Nanoparticles and Derived Nanomaterials for Catalysis An exploration of Dynamic Catalysis and the Interface Between Molecular and Heterogeneous Catalysts A practical discussion of Metal Nanoparticles in Water: A Relevant Toolbox for Green Catalysis Organometallic Metal Nanoparticles for Catalysis A concise treatment of the opportunities and challenges of CO2 Hydrogenation to Oxygenated Chemicals Over Supported Nanoparticle Catalysts Perfect for catalytic, organic, inorganic, and physical chemists, Nanoparticles in Catalysis will also earn a place in the libraries of chemists working with organometallics and materials scientists seeking a one-stop resource with expert knowledge on the synthesis and characterization of nanoparticle catalysis.

Catalysis by Materials with Well-Defined Structures

Catalysis by Materials with Well-Defined Structures
A Book

by Zili Wu,Steven H. Overbury

  • Publisher : Elsevier Science Limited
  • Release : 2015-04-02
  • Pages : 392
  • ISBN : 9780128012178
  • Language : En, Es, Fr & De
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Catalysis by Materials with Well-Defined Structures examines the latest developments in the use of model systems in fundamental catalytic science. A team of prominent experts provides authoritative, first-hand information, helping readers better understand heterogeneous catalysis by utilizing model catalysts based on uniformly nanostructured materials. The text addresses topics and issues related to material synthesis, characterization, catalytic reactions, surface chemistry, mechanism, and theoretical modeling, and features a comprehensive review of recent advances in catalytic studies on nanomaterials with well-defined structures, including nanoshaped metals and metal oxides, nanoclusters, and single sites in the areas of heterogeneous thermal catalysis, photocatalysis, and electrocatalysis. Users will find this book to be an invaluable, authoritative source of information for both the surface scientist and the catalysis practitioner Outlines the importance of nanomaterials and their potential as catalysts Provides detailed information on synthesis and characterization of nanomaterials with well-defined structures, relating surface activity to catalytic activity Details how to establish the structure-catalysis relationship and how to reveal the surface chemistry and surface structure of catalysts Offers examples on various in situ characterization instrumental techniques Includes in-depth theoretical modeling utilizing advanced Density Functional Theory (DFT) methods

Metal Nanoparticles for Catalysis

Metal Nanoparticles for Catalysis
Advances and Applications

by Franklin (Feng) Tao

  • Publisher : Royal Society of Chemistry
  • Release : 2014-06-30
  • Pages : 285
  • ISBN : 1782620338
  • Language : En, Es, Fr & De
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Catalysis is a central topic in chemical transformation and energy conversion. Thanks to the spectacular achievements of colloidal chemistry and the synthesis of nanomaterials over the last two decades, there have also been significant advances in nanoparticle catalysis. Catalysis on different metal nanostructures with well-defined structures and composition has been extensively studied. Metal nanocrystals synthesized with colloidal chemistry exhibit different catalytic performances in contrast to metal nanoparticles prepared with impregnation or deposition precipitation. Additionally, theoretical approaches in predicting catalysis performance and understanding catalytic mechanism on these metal nanocatalysts have made significant progress. Metal Nanoparticles for Catalysis is a comprehensive text on catalysis on Nanoparticles, looking at both their synthesis and applications. Chapter topics include nanoreactor catalysis; Pd nanoparticles in C-C coupling reactions; metal salt-based gold nanocatalysts; theoretical insights into metal nanocatalysts; and nanoparticle mediated clock reaction. This book bridges the gap between nanomaterials synthesis and characterization, and catalysis. As such, this text will be a valuable resource for postgraduate students and researchers in these exciting fields.

Atomically Precise Metal Nanoclusters

Atomically Precise Metal Nanoclusters
A Book

by Zhikun Wu,Rongchao Jin

  • Publisher : Morgan & Claypool Publishers
  • Release : 2020-11-06
  • Pages : 139
  • ISBN : 1636390250
  • Language : En, Es, Fr & De
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Atomically precise metal nanocluster research has emerged as a new frontier. This book serves as an introduction to metal nanoclusters protected by ligands. The authors have summarized the synthesis principles and methods, the characterization methods and new physicochemical properties, and some potential applications. By pursuing atomic precision, such nanocluster materials provide unprecedented opportunities for establishing precise relationships between the atomic-level structures and the properties. The book should be accessible to senior undergraduate and graduate students, researchers in various fields (e.g., chemistry, physics, materials, biomedicine, and engineering), R&D scientists, and science policy makers.

Creation of New Metal Nanoparticles and Their Hydrogen-Storage and Catalytic Properties

Creation of New Metal Nanoparticles and Their Hydrogen-Storage and Catalytic Properties
A Book

by Kohei Kusada

  • Publisher : Springer
  • Release : 2014-07-16
  • Pages : 78
  • ISBN : 4431550879
  • Language : En, Es, Fr & De
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This thesis reports the discovery of metal nanoparticles having new structures that do not exist in bulk state and that exhibit hydrogen storage ability or CO oxidation activity. Research into the reaction of hydrogen with metals has attracted much attention because of potential applications as effective hydrogen storage materials, as permeable films, or as catalysts for hydrogenation. Also, CO oxidation catalysts have been extensively developed because of their importance to CO removal from car exhaust or fuel-cell systems. At the same time, atomic-level (solid solution) alloying has the advantage of being able to continuously control chemical and physical properties of elements by changing compositions and/or combinations of constituent elements. This thesis provides a novel strategy for the basis of inter-elemental fusion to create highly efficient functional materials for energy and material conversions.

Morphological, Compositional, and Shape Control of Materials for Catalysis

Morphological, Compositional, and Shape Control of Materials for Catalysis
A Book

by Paolo Fornasiero,Matteo Cargnello

  • Publisher : Elsevier
  • Release : 2017-05-23
  • Pages : 710
  • ISBN : 0323446655
  • Language : En, Es, Fr & De
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Morphological, Compositional, and Shape Control of Materials for Catalysis, Volume 177, the latest in the Studies in Surface Science and Catalysis series, documents the fast-growing developments in the synthesis, characterization, and utilization of nanostructures for catalysis. The book provides essential background on using well-defined materials for catalysis and presents exciting new paradigms in the preparation and application of catalytic materials, with an emphasis on how structure determines catalytic properties. In addition, the book uniquely features discussions on the future of the field, with ample space for future directions detailed in each chapter. Presents the latest paradigms in the preparation and application of catalytic materials Provides essential background on using well-defined materials for catalysis Features discussion of future directions at the end of each chapter

Plasmonic Catalysis

Plasmonic Catalysis
From Fundamentals to Applications

by Pedro H.C. Camargo,Emiliano Cortés

  • Publisher : John Wiley & Sons
  • Release : 2021-07-13
  • Pages : 352
  • ISBN : 352734750X
  • Language : En, Es, Fr & De
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Explore this comprehensive discussion of the foundational and advanced topics in plasmonic catalysis from two leaders in the field Plasmonic Catalysis: From Fundamentals to Applications delivers a thorough treatment of plasmonic catalysis, from its theoretical foundations to myriad applications in industry and academia. In addition to the fundamentals, the book covers the theory, properties, synthesis, and various reaction types of plasmonic catalysis. It also covers its applications in reactions including oxidation, reduction, nitrogen fixation, CO2 reduction, and more. The book characterizes plasmonic catalytic systems and describes their properties, tackling the integration of conventional methods as well as new methods able to unravel the optical, electronic, and chemical properties of these systems. It also describes the fundamentals of controlled synthesis of metal nanoparticles relevant to plasmonic catalysis, as well as practical examples thereof. Plasmonic Catalysis covers a wide variety of other practical topics in the field, including hydrogenation reactions and the harvesting of LSPR-excited charge carriers. Readers will also benefit from the inclusion of: A thorough introduction to plasmonic catalysis, a theory of plasmons for catalysis and mechanisms, as well as optical properties of plasmonic-catalytic nanostructures An exploration of the synthesis of plasmonic nanoparticles for photo and electro catalysis, as well as plasmonic catalysis towards oxidation reactions and hydrogenation reactions Discussions of plasmonic catalysis for multi-electron processes and artificial photosynthesis and N2 fixation An examination of control over reaction selectivity in plasmonic catalysis Perfect for catalytic chemists, materials scientists, photochemists, and physical chemists, Plasmonic Catalysis: From Fundamentals to Applications will also earn a place in the libraries of physicists who seek a one-stop resource to enhance their understanding of applications in plasmonic catalysis.

Semiconductor Nanoclusters - Physical, Chemical, and Catalytic Aspects

Semiconductor Nanoclusters - Physical, Chemical, and Catalytic Aspects
A Book

by P.V. Kamat,D. Meisel

  • Publisher : Elsevier Science Serials
  • Release : 1997
  • Pages : 474
  • ISBN : 9876543210XXX
  • Language : En, Es, Fr & De
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Reflecting the shift over the past decade from theoretical descriptions to field utilizations of nanostructure-based devices, researchers present the salient features of nanocrystalline semiconductor materials for scientists, engineers, and advanced graduate students in physical chemistry and materials science. The topics include preparing and characterizing nanoparticles, sonochemistry in colloidal systems, the pseudopotential theory of nanometer silicon quantum dots, size quantization in semiconductor films deposited by chemical solutions, electronic junctions, analytical chemistry, semiconductor-mediated photocatalysis for organic synthesis, and applications in purifying air. Annotation copyrighted by Book News, Inc., Portland, OR

Current Trends of Surface Science and Catalysis

Current Trends of Surface Science and Catalysis
A Book

by Jeong Young Park

  • Publisher : Springer Science & Business Media
  • Release : 2013-10-23
  • Pages : 262
  • ISBN : 1461487420
  • Language : En, Es, Fr & De
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This unique book covers the latest surface science studies on model catalysts, including single crystals, non-colloidal nanocatalysts, and nanoparticles in various forms with the control of size, shape and composition. This book addresses the issue of bridging “materials and pressure gaps” and also discusses the important issue of metal-oxide interface and hot electron flows in heterogeneous catalysis. The current development of in-situ surface techniques that is relevant to bridging “pressure gaps” is also highlighted.

Nanotechnology in Catalysis

Nanotechnology in Catalysis
Applications in the Chemical Industry, Energy Development, and Environment Protection

by Bert Sels,Marcel Van de Voorde

  • Publisher : John Wiley & Sons
  • Release : 2017-06-20
  • Pages : 1500
  • ISBN : 352769983X
  • Language : En, Es, Fr & De
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Reflecting the R&D efforts in the field that have resulted in a plethora of novel applications over the past decade, this handbook gives a comprehensive overview of the tangible benefits of nanotechnology in catalysis. By bridging fundamental research and industrial development, it provides a unique perspective on this scientifically and economically important field. While the first three parts are devoted to preparation and characterization of nanocatalysts, the final three provide in-depth insights into their applications in the fine chemicals industry, the energy industry, and for environmental protection, with expert authors reporting on real-life applications that are on the brink of commercialization. Timely reading for catalytic chemists, materials scientists, chemists in industry, and process engineers.

Nanoparticles in Catalysis

Nanoparticles in Catalysis
Advances in Synthesis and Applications

by Karine Philippot,Alain Roucoux

  • Publisher : John Wiley & Sons
  • Release : 2021-04-05
  • Pages : 368
  • ISBN : 3527346074
  • Language : En, Es, Fr & De
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Discover an essential overview of recent advances and trends in nanoparticle catalysis Catalysis in the presence of metal nanoparticles is an important and rapidly developing research field at the frontier of homogeneous and heterogeneous catalysis. In Nanoparticles in Catalysis, accomplished chemists and authors Karine Philippot and Alain Roucoux deliver a comprehensive guide to the key aspects of nanoparticle catalysis, ranging from synthesis, activation methodology, characterization, and theoretical modeling, to application in important catalytic reactions, like hydrogen production and biomass conversion. The book offers readers a review of modern and efficient tools for the synthesis of nanoparticles in solution or onto supports. It emphasizes the application of metal nanoparticles in important catalytic reactions and includes chapters on activation methodology and supported nanoclusters. Written by an international team of leading voices in the field, Nanoparticles in Catalysis is an indispensable resource for researchers and professionals in academia and industry alike. Readers will also benefit from the inclusion of: A thorough introduction to New Trends in the Design of Metal Nanoparticles and Derived Nanomaterials for Catalysis An exploration of Dynamic Catalysis and the Interface Between Molecular and Heterogeneous Catalysts A practical discussion of Metal Nanoparticles in Water: A Relevant Toolbox for Green Catalysis A concise treatment of the opportunities and challenges of CO2 Hydrogenation to Oxygenated Chemicals Over Supported Nanoparticle Catalysts Perfect for catalytic, organic, inorganic, and physical chemists, Nanoparticles in Catalysis will also earn a place in the libraries of chemists working with organometallics and materials scientists seeking a one-stop resource with expert knowledge on the synthesis and characterization of nanoparticle catalysis.

CeO2-supported Gold Catalysts for CO Oxidation

CeO2-supported Gold Catalysts for CO Oxidation
Synthesis, Reactivity, Activation, and Characterization for Site-isolated Mononuclear Species and Clusters

by Veronica Illeana Aguilar-Guerrero

  • Publisher : Unknown Publisher
  • Release : 2008
  • Pages : 378
  • ISBN : 9876543210XXX
  • Language : En, Es, Fr & De
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Nanoparticles and Catalysis

Nanoparticles and Catalysis
A Book

by Didier Astruc

  • Publisher : John Wiley & Sons
  • Release : 2008-06-25
  • Pages : 663
  • ISBN : 3527621334
  • Language : En, Es, Fr & De
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Written by international experts, this monograph combines two of the most important aspects of modern chemistry, presenting the latest knowledge on these environmental friendly applications. This result is a comprehensive overview of the application of nanoparticles in catalysis, focusing on synthesis and the most important reaction types, providing all the information needed by catalytic, organic and solid state chemists, as well as those working with or on organometallics, materials scientists, and chemists in industry.

New and Future Developments in Catalysis

New and Future Developments in Catalysis
Chapter 7. Transition Metal Nanoparticles as Catalyst in Hydrogen Generation from the Boron-Based Hydrogen Storage Materials

by Saim Özkar

  • Publisher : Elsevier Inc. Chapters
  • Release : 2013-07-11
  • Pages : 550
  • ISBN : 0128082089
  • Language : En, Es, Fr & De
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Silver Nanoparticles

Silver Nanoparticles
From Silver Halide Photography to Plasmonics

by Tadaaki Tani

  • Publisher : OUP Oxford
  • Release : 2015-09-17
  • Pages : 240
  • ISBN : 019102399X
  • Language : En, Es, Fr & De
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Nanoscience and nanotechnology concern themselves with the research and application of extremely small things and can be used across all scientific fields such as physics, chemistry, biology, material science and engineering. Nanoparticles are of great scientific interest as they provide a bridge between bulk materials and atomic or molecular structures. Interesting and unexpected properties of nanoparticles are largely due to the large surface area of the material. Nanoparticles of noble metals including silver (Ag) attract the interest of many researchers owing to their high potential for plasmonic devices in future. On the other hand, nanoparticles of silver (Ag) and silver halides (AgX) have played central roles and have been extensively studied for many years in silver halide (AgX) photography. Combining knowledge of nanoparticles of Ag and related materials in plasmonics and AgX photography, this book reinforces already existing knowledge, but also presents new ideas for metal nanoparticles in plasmonics. The first part examines the structure and formation of nanoparticles of Ag and related materials. Systematic descriptions of the structure and preparation of Ag, Au, and other noble metal nanoparticles for plasmonics are followed by and related to those of nanoparticles of Ag and AgX in AgX photography. The exploration of the structure and preparation of Ag and AgX nanoparticles in photography incorporates nanoparticles with widely varied sizes, shapes, and structures, and formation processes from nucleation to growth. The second part describes the properties and performances of nanoparticles of Ag and related materials, including chapters on light absorption and scattering, catalysis, photovoltaic effects, and stability. The accumulated knowledge of many years of research in AgX photography is analysed and explained to deepen the reader's knowledge on metal nanoparticles for plasmonics, catalysis, and photovoltaics with new ideas arising from the interaction between them.

Atomically Precise Metal Nanoclusters

Atomically Precise Metal Nanoclusters
A Book

by Zhikun Wu,Rongchao Jin

  • Publisher : Unknown Publisher
  • Release : 2020-11-06
  • Pages : 139
  • ISBN : 9781636390260
  • Language : En, Es, Fr & De
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Atomically precise metal nanocluster research has emerged as a new frontier. This book serves as an introduction to metal nanoclusters protected by ligands. The authors have summarized the synthesis principles and methods, the characterization methods and new physicochemical properties, and some potential applications. By pursuing atomic precision, such nanocluster materials provide unprecedented opportunities for establishing precise relationships between the atomic-level structures and the properties. The book should be accessible to senior undergraduate and graduate students, researchers in various fields (e.g., chemistry, physics, materials, biomedicine, and engineering), R&D scientists, and science policy makers.

Noble Metal-Based Nanocomposites

Noble Metal-Based Nanocomposites
Preparation and Applications

by Jun Yang

  • Publisher : John Wiley & Sons
  • Release : 2019-06-10
  • Pages : 456
  • ISBN : 3527344527
  • Language : En, Es, Fr & De
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Provides a systematic and coherent picture of the solution-based methods for the preparation of noble metal-based composite nanomaterials, their characterization, and potential applications in electrocatalysis Within the last decade, the development of wet-chemistry methods has led to the blossom of research in composite nanomaterials. However, the design and synthesis of composite nanomaterials with controlled properties remains a significant challenge. This book summarizes the solution-based methods for the preparation of noble metal-based composite nanomaterials. It examines their characterization, as well as their use in electrocatalysis. It also discusses the intrinsic relationship between the catalytic properties and the physical /chemical effects in the composite materials, and offers some perspectives for the future development of metal-based composite nanomaterials. In addition, the book not only provides a systematic and coherent picture of this field, but also inspires rethinking of the current processing technologies. Noble Metal-Based Nanocomposites: Preparation and Applications offers in-depth chapter coverage of ethanol-mediated phase transfer of metal ions and nanoparticles. It presents the full range of nanocomposites consisting of chalcogenide semiconductors and gold, silver sulfide, or other noble metals. It also examines core-shell structured cadmium selenide-platinum nanocomposites; Pt-containing Ag2S-noble metal nanocomposites for direct methanol fuel cells operated at high fuel concentrations; and nanocomposites consisting of metal oxides and noble metals. In addition, the book looks at scientific issues derived from noble metal-based nanocomposites. -Covers all of the preparations of noble metal-based nanocomposites and their numerous applications -Highlights some of the recent breakthroughs in the design, engineering, and applications of noble metal-based nanocomposites -Appeals to a wide range audience, especially researchers in the areas of catalysis, chemistry, chemical engineering, materials synthesis and characterization, and fuel cell Noble Metal-Based Nanocomposites: Preparation and Applications is an excellent book for inorganic chemists, materials scientists, catalytic chemists, chemical engineers, and those interested in the subject.

Noble Metal-Metal Oxide Hybrid Nanoparticles

Noble Metal-Metal Oxide Hybrid Nanoparticles
Fundamentals and Applications

by Satyabrata Mohapatra,Tuan Anh Nguyen,Phuong Nguyen-Tri

  • Publisher : Elsevier
  • Release : 2018-10-11
  • Pages : 674
  • ISBN : 0128141352
  • Language : En, Es, Fr & De
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Noble Metal-Metal Oxide Hybrid Nanoparticles: Fundamentals and Applications sets out concepts and emerging applications of hybrid nanoparticles in biomedicine, antibacterial, energy storage and electronics. The hybridization of noble metals (Gold, Silver, Palladium and Platinum) with metal-oxide nanoparticles exhibits superior features when compared to individual nanoparticles. In some cases, metal oxides act as semiconductors, such as nano zinc oxide or titanium oxide nanoparticles, where their hybridization with silver nanoparticles, enhanced significantly their photocatalytic efficiency. The book highlights how such nanomaterials are used for practical applications. Examines the properties of metal-metal oxide hybrid nanoparticles that make them so adaptable Explores the mechanisms by which nanoparticles interact with each other, showing how these can be exploited for practical applications Shows how metal oxide hybrid nanomaterials are used in a range of industry sectors, including energy, the environment and healthcare

Inorganic Nanoparticles

Inorganic Nanoparticles
Synthesis, Applications, and Perspectives

by Claudia Altavilla,Enrico Ciliberto

  • Publisher : CRC Press
  • Release : 2017-12-19
  • Pages : 576
  • ISBN : 1439817626
  • Language : En, Es, Fr & De
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Among the various nanomaterials, inorganic nanoparticles are extremely important in modern technologies. They can be easily and cheaply synthesized and mass produced, and for this reason, they can also be more readily integrated into applications. Inorganic Nanoparticles: Synthesis, Applications, and Perspectives presents an overview of these special materials and explores the myriad ways in which they are used. It addresses a wide range of topics, including: Application of nanoparticles in magnetic storage media Use of metal and oxide nanoparticles to improve performance of oxide thin films as conducting media in commercial gas and vapor sensors Advances in semiconductors for light-emitting devices and other areas related to the energy sector, such as solar energy and energy storage devices (fuel cells, rechargeable batteries, etc.) The expanding role of nanosized particles in the field of catalysis, art conservation, and biomedicine The book’s contributors address the growing global interest in the application of inorganic nanoparticles in various technological sectors. Discussing advances in materials, device fabrication, and large-scale production—all of which are urgently required to reduce global energy demands—they cover innovations in areas such as solid-state lighting, detailing how it still offers higher efficiency but higher costs, compared to conventional lighting. They also address the impact of nanotechnology in the biomedical field, focusing on topics such as quantum dots for bioimaging, nanoparticle-based cancer therapy, drug delivery, antibacterial agents, and more. Fills the informational gap on the wide range of applications for inorganic nanoparticles in areas including biomedicine, electronics, storage media, conservation of cultural heritage, optics, textiles, and cosmetics Assembling work from an array of experts at the top of their respective fields, this book delivers a useful analysis of the vast scope of existing and potential applications for inorganic nanoparticles. Versatile as either a professional research resource or textbook, this effective tool elucidates fundamentals and current advances associated with design, characterization, and application development of this promising and ever-evolving device.