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Organotransition Metal Chemistry: Applications to Organic Synthesis

Organotransition Metal Chemistry: Applications to Organic Synthesis
Applications to Organic Synthesis

by S. G. Davies

  • Publisher : Elsevier
  • Release : 2013-10-22
  • Pages : 430
  • ISBN : 1483285847
  • Language : En, Es, Fr & De
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Although organotransition metal chemistry has been developing rapidly over the past 20 years, it is only recently that applications of transition metal complexes to organic synthesis have started to be exploited. This unique book provides an introduction to organometallic chemistry for chemists who have little or no experience in the field, describes the work that has already been done using organotransition metal complexes for synthesis, and indicates to organic and organometallic chemists the type of synthetic problems that can be solved using organometallic compounds. It covers all major advances that have been made in this rapidly expanding area of chemistry, including not only reactions that already have well established applications for synthesis but also many recently discovered potentially useful reactions, providing a survey of recent literature.

Organotransition-Metal Chemistry

Organotransition-Metal Chemistry
A Book

by Yoshio Ishii

  • Publisher : Springer Science & Business Media
  • Release : 2012-12-06
  • Pages : 398
  • ISBN : 1468421425
  • Language : En, Es, Fr & De
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Synthesis of Organotransition Metals.- Metallocarboranes: Past, Present, and Future.- Novel Rhodium and Palladium Complexes with Benzoyl and Thiobenzoyl Isocyanates as Ligands.- Polycyanovinyl Transition Metal Derivatives.- A New Preparation of Organocopper(I)-Isonitrile Complexes and Their Reactions.- An Unusual Behavior of?-Vinyl Alcohol Complexes of Transition Metals.- The Mode of Formation of Transition Metal to Carbon Bonds by Oxidative Addition.- Organoactinides: Coordination Patterns and Chemical Reactivity.- Recent Developments in Chemistry of Organolanthanides and Organoactinides.- C.

Organotransition Metal Chemistry

Organotransition Metal Chemistry
Fundamental Concepts and Applications

by Akio Yamamoto

  • Publisher : Wiley-Interscience
  • Release : 1986
  • Pages : 455
  • ISBN : 9876543210XXX
  • Language : En, Es, Fr & De
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A systematic, readable treatment of organotransition metal chemistry that provides students, teachers, and practicing chemists with an understanding of basic concepts in catalysis and synthetic procedures using transition metal reagents. Covers basic principles of coordination chemistry, organometallic compounds of transition metals and non-transition metals, reactions, industrial applications, use in synthesis, methods of manipulation for air-sensitive compounds, and an overview of related topics. Well illustrated with figures and formulae.

Organotransition Metal Chemistry

Organotransition Metal Chemistry
A Book

by Anthony F. Hill,A. Hill

  • Publisher : Royal Society of Chemistry
  • Release : 2002
  • Pages : 185
  • ISBN : 9780854046225
  • Language : En, Es, Fr & De
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This book aims to introduce undergraduates to the utility of organotransition metal chemistry, a discipline of importance to scientists in a variety of industry sectors.

Organotransition Metal Chemistry: From Bonding to Catalysis

Organotransition Metal Chemistry: From Bonding to Catalysis
A Book

by John F. Hartwig

  • Publisher : Univ Science Books
  • Release : 2010-02-10
  • Pages : 1127
  • ISBN : 9876543210XXX
  • Language : En, Es, Fr & De
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Based on Collman et al.'s best-selling classic book, Principles and Applications of Organotransition Metal Chemistry, Hartwig's text consists of new or thoroughly updated and restructured chapters and provides an in-depth view into mechanism, reaction scope, and applications. It covers the most important developments in the field over the last twenty years with great clarity with a selective, but thorough and authoritative coverage of the fundamentals of organometallic chemistry, the elementary reactions of these complexes, and many catalytic processes occurring through organometallic intermediates, making this the Organotransition Metal Chemistry text for a new generation of scientists.

Transition Metals in the Synthesis of Complex Organic Molecules

Transition Metals in the Synthesis of Complex Organic Molecules
A Book

by Louis S. Hegedus

  • Publisher : University Science Books
  • Release : 1999
  • Pages : 337
  • ISBN : 9781891389047
  • Language : En, Es, Fr & De
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This second edition offers easy access to the field of organotransition metal chemistry. The book covers the basics of transition metal chemistry, giving a practical introduction to organotransition reaction mechanisms.

Transition Metal Reagents and Catalysts

Transition Metal Reagents and Catalysts
Innovations in Organic Synthesis

by Jiro Tsuji

  • Publisher : John Wiley & Sons
  • Release : 2002-08-16
  • Pages : 496
  • ISBN : 9780471560272
  • Language : En, Es, Fr & De
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Transition Metal Reagents and Catalysts Innovations in Organic Synthesis Jiro Tsuji Emeritus Professor, Tokyo Institute of Technology, Japan Numerous innovative and practical synthetic methods using transition metal complexes as either catalysts or reagents have been developed over the last 35 years. Transition Metal Reagents and Catalysts combines the varied applications of transition metal complexes in a unique and timely book in this rapidly advancing area of organic synthesis. This text is an easily understandable and enjoyable read for organic chemists who are not yet familiar with organo-transition metal chemistry. Transition Metal Reagents and Catalysts presents: * Complete coverage of nearly 35 years of transition metal complex chemistry * An in-depth treatment of many innovative synthetic methodologies * A rational classification of all reactions according to substrates and reaction mechanisms * Examples of important applications of transition metal catalysed reactions. A knowledge of organic synthesis using transition metal complexes is a must for all synthetic organic chemists. Written for chemists who wish to apply novel synthetic methods using transition metal complexes to solve problems in organic and pharmaceutical chemistry, such as synthesis of fine and bulk chemicals and natural products, Transition Metal Reagents and Catalysts is an essential reference source and an indispensible research companion.

Organotransition Metal Chemistry A Mechanistic Approach

Organotransition Metal Chemistry A Mechanistic Approach
A Book

by Richard Heck

  • Publisher : Elsevier
  • Release : 2012-12-02
  • Pages : 350
  • ISBN : 0323154700
  • Language : En, Es, Fr & De
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Organotransition Metal Chemistry: A Mechanistic Approach describes a mechanistic approach to the study of the chemistry of organotransition metals. Organotransition metals are discussed in relation to their reactions with specific functional groups or types of compounds rather than by metals. Topics covered include the formation of hydrogen and carbon bonds to transition metals; reactions of transition metal δ- and π-bonded derivatives; and addition and elimination reactions of olefinic compounds. This book is comprised of 10 chapters and begins with a historical overview of organotransition metal chemistry, together with the unique chemistry of transition metals and mechanisms of ligand replacements. The following chapters discuss the methods of preparation of hydrido complexes and carbon-transition metal bonds; homogeneous hydrogenation reactions; isomerization, dimerization, oligomerization, and polymerization of olefins; and reactions of dienes, trienes, and tetraenes with transition metal compounds. Transition metal reactions with acetylenes and carbon monoxide as well as organic carbonyl compounds are also examined. This monograph should be of value to organic chemists as well as students and researchers of organic chemistry.

Principles and Applications of Organotransition Metal Chemistry

Principles and Applications of Organotransition Metal Chemistry
A Book

by James Paddock Collman,Louis S. Hegedus,Jack R. Norton,Richard G. Finke

  • Publisher : Univ Science Books
  • Release : 1987
  • Pages : 989
  • ISBN : 9876543210XXX
  • Language : En, Es, Fr & De
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This textbook introduces students and experienced chemists to a rapidly growing interdisciplinary subject. It incorporates a thorough revision of the earlier edition, and includes all new developments.

The Organometallic Chemistry of the Transition Metals

The Organometallic Chemistry of the Transition Metals
A Book

by Robert H. Crabtree

  • Publisher : John Wiley & Sons
  • Release : 2009-04-06
  • Pages : 520
  • ISBN : 0470257628
  • Language : En, Es, Fr & De
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"One impressive and compressive book. . . . This review would have to be book size to do full justice to all the insights in this volume." —Journal of Metals Online Fully updated and expanded to reflect recent advances, this Fifth Edition of the classic text provides students and professional chemists with a comprehensive introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and?detailed descriptions of contemporary applications. With increased focus on organic synthesis applications, nanoparticle science, and green chemistry, the Fifth Edition brings this vital resource up to date. New to the Fifth Edition: Chapters have been updated with relevant examples in the field, modern trends, and new applications; the organic applications chapter has been completely rewritten New end-of-chapter problems, along with their solutions Coverage enhanced with developments in nanoparticle science Increased focus on green chemistry An unparalleled pedagogic resource as well as a valuable working reference for professional chemists, with comprehensive coverage and up-to-date information, students and researchers?in organic and organometallic chemistry will turn to The Organometallic Chemistry of the Transition Metals, Fifth Edition for the critical information they need on organometallic compounds, their preparation, and their use in synthesis.

Landmarks in Organo-Transition Metal Chemistry

Landmarks in Organo-Transition Metal Chemistry
A Personal View

by Helmut Werner

  • Publisher : Springer Science & Business Media
  • Release : 2008-12-16
  • Pages : 348
  • ISBN : 0387098488
  • Language : En, Es, Fr & De
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Since the discovery of ferrocene and the sandwich-type complexes, the development of organometallic chemistry took its course like an avalanche and became one of the scientific success stories of the second half of the twentieth century. Based on this development, the traditional boundaries between inorganic and organic chemistry gradually disappeared and a rebirth of the nowadays highly important field of homogeneous catalysis occurred. It is fair to say that despite the fact that the key discovery, which sparked it all off, was made more than 50 years ago, organometallic chemistry remains a young and lively discipline.

Organometallic Chemistry

Organometallic Chemistry
A Book

by R. C. Mehrotra

  • Publisher : New Age International
  • Release : 2007
  • Pages : 632
  • ISBN : 9788122412581
  • Language : En, Es, Fr & De
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The Book Is A Revised Edition Of A Lucid And Stimulating Introductory Account Of Organometallic Chemistry, An Exciting And Rapidly Developing Interdisciplinary Branch Of Science.A Characteristic Feature Of This Book Is The Presentation Of An Integrated (Covering Different Facets Usually Dealt With Either In Organic Or/And Inorganic Texts) View Of The Rapidly Developing Field Of Organometallic Chemistry. Attempts Have Been Made To Choose The Latest Examples To Illustrate The Fundamental Properties As Well As The Synthetic Procedures Of Organometallic Chemistry. Other Features Include: (A) An Interesting Brief Historical Background Of The Subject Including Some Quotations From Relevant Nobel Lecture Accounts Of Epoch Making Advances By The Discoverers Themselves, (B) The Adoption As Far As Possible Of The Iupac Rules Of Nomenclature, (C) A Brief Account Of The Rapidly Emerging Organometallic Chemistry Of The F-Elements, And (D) Inclusion Of Study Questions At The End Of Each Chapter.During The Revision Of The Book, The Latest Examples Have Replaced The Older Ones Wherever Feasible. The Book Would Be Extremely Useful As A Basic Text For B.Sc. (Hons.) And M.Sc. Chemistry Students.

Organometallic Chemistry

Organometallic Chemistry
A Book

by Ian J. S. Fairlamb,Jason M. Lynam

  • Publisher : Royal Society of Chemistry
  • Release : 2012-06-01
  • Pages : 127
  • ISBN : 1849733767
  • Language : En, Es, Fr & De
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A series of critical reviews and perspectives focussing on specific aspects of organometallic chemistry interfacing with other fields of study are provided. For this volume, the critical reviews cover topics such as the activation of "inert" carbon-hydrogen bonds, ligand design and organometallic radical species. For example, Charlie O'Hara discusses how mixed-metal compounds may perform the highly selective activation of C-H bonds and, in particular, how synergic relationships between various metals are crucial to this approach. The chemistry of a remarkable series of air-stable chiral primary phosphine ligands is discussed in some depth by Rachel Hiney, Arne Ficks, Helge M ller-Bunz, Declan Gilheany and Lee Higham. This article focuses on the preparation of these ligands and also how they may be applied in various catalytic applications. Bas De Bruin reports on how ligand radical reactivity can be employed in synthetic organometallic chemistry and catalysis to achieve selectivity in radical-type transformations. As well as highlighting ligand-centered radical transformations in open-shell transition metals, an overview of the catalytic mechanism of Co(II)-catalysed olefin cyclopropanation is given, showing that enzyme-like cooperative metal-ligand-radical reactivity is no longer limited to real enzymes. Valuable and informative comprehensive reviews in the field of organometallic chemistry are also covered in this volume. For example, organolithium and organocuprate chemistry are reviewed by Joanna Haywood and Andrew Wheatley; aspects in Group 2 (Be-Ba) and Group 12 (Zn-Hg) compounds by Robert Less, Rebecca Melen and Dominic Wright; metal clusters by Mark Humphrey and Marie Cifuentes; and recent developments in the chemistry of the elements of Group 14 - focusing on low-coordination number compounds by Richard Layfield. This volume therefore covers many synthetic and applied aspects of modern organometallic chemistry which ought to be of interest to inorganic, organic and applied catalysis fields."

Organometallic Chemistry

Organometallic Chemistry
A Book

by M. Green,Turpin

  • Publisher : Royal Society of Chemistry
  • Release : 2000
  • Pages : 564
  • ISBN : 9780854043231
  • Language : En, Es, Fr & De
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This Specialist Periodical Report aims to reflect the growing interest in the potential of organometallic chemistry.

Principles of Organometallic Chemistry

Principles of Organometallic Chemistry
A Book

by P. Powell

  • Publisher : Springer
  • Release : 2013-12-21
  • Pages : 414
  • ISBN : 9400911971
  • Language : En, Es, Fr & De
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Organic Synthesis Highlights

Organic Synthesis Highlights
A Book

by Johann Mulzer

  • Publisher : Vch Pub
  • Release : 1991
  • Pages : 410
  • ISBN : 9876543210XXX
  • Language : En, Es, Fr & De
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Like its predecessor, Organic Synthesis Highlights II surveys recent accomplishments and current trends in synthetic organic chemistry. Part I describes new methods and reagents including asymmetric carbon-carbon bond formation with metallocenes and with enzymes, via temporary silicon connections, and by means of carbohydrate complexes. Part II describes landmarks in the synthesis of natural products and surveys synthetic strategies to different classes of natural products. The forty essays in this volume bear witness to the creativity and talent which have led to the recent advances in the field. Both advanced students and researchers active in the field will welcome this as a source of ideas and inspiration.

Transition Metals in Organic Synthesis

Transition Metals in Organic Synthesis
Conference Papers of the International Seminar on Modern Synthetic Methods 1983, Interlaken, May 5th/6th, 1983

by Rolf Scheffold

  • Publisher : Unknown Publisher
  • Release : 1983
  • Pages : 440
  • ISBN : 9876543210XXX
  • Language : En, Es, Fr & De
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Library of Congress Subject Headings

Library of Congress Subject Headings
A Book

by Library of Congress,Library of Congress. Office for Subject Cataloging Policy

  • Publisher : Unknown Publisher
  • Release : 2012
  • Pages : 329
  • ISBN : 9876543210XXX
  • Language : En, Es, Fr & De
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Organotransition Metal Chemistry

Organotransition Metal Chemistry
A Book

by Anthony Hill

  • Publisher : Wiley-RSC
  • Release : 2002-08-30
  • Pages : 185
  • ISBN : 9780471281634
  • Language : En, Es, Fr & De
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What do a pharmaceutical, polymer and solid state chemist have in common? Organometallic chemistry of course, since progress in their diverse fields has at many times relied on this. It is a discipline which stands at the crossroads of so many branches of chemistry, with industrial applications ranging from the gram to megatonne scale. Organotransition Metal Chemistry aims to introduce undergraduates to the utility of organotransition metal chemistry, a discipline of importance to scientists and technologists in a variety of industry sectors. The main focus will be on the reactivity of organometallic compounds of the transition metals, supported by discussion of structure and bonding and the implications. The aim, on completion of the course, is that a student will be equipped to recognize the key classes of organometallic compound, their methods of characterization, possible synthetic routes and anticipated reactivity.

Transition Metal Carbyne Complexes

Transition Metal Carbyne Complexes
A Book

by F.R. Kreißl,Fritz R. Kreißl

  • Publisher : Springer Science & Business Media
  • Release : 1993-03-31
  • Pages : 268
  • ISBN : 9780792322122
  • Language : En, Es, Fr & De
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This book presents an advanced state-of-the-art report on the Fischer and Schrock type carbyne complexes and demonstrates their wide application to organic and organometallic synthesis, as well as their considerable role in metathesis. Most of the articles are written by leading researchers in this field, describing their fascinating research in their own words. This carbyne book discusses in detail the breadth and diversity of metal-carbon multiple bond chemistry of different d and f-block elements. Besides theoretical, structural, photochemical and electrochemical studies, this volume provides a fascinating introduction to heterometallic carbon-bridged compounds to conjugated complexes and polymers derived from metal-carbyne building blocks. An extensive part of this book discusses aspects of olefin metathesis, metal-induced addition, cycloaddition and carbon-carbon coupling reactions by well-characterized carbene and carbyne complexes. (abstract) This book presents an advanced state-of-the-art report on the Fischer and Schrock type carbyne complexes, discussing specific aspects of the metal carbon multiple bond chemistry of different d and f-block elements, such as synthetic, theoretical, structural, photochemical and electrochemical studies. Special chapters focus on catalysis and olefin metathesis as well as metal induced addition, cycloaddition and carbon-carbon coupling reactions.