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Organotransition Metal Chemistry: From Bonding to Catalysis

Organotransition Metal Chemistry: From Bonding to Catalysis
A Book

by John F. Hartwig

  • Publisher : Univ Science Books
  • Release : 2010-02-10
  • Pages : 1127
  • ISBN : 9876543210XXX
  • Language : En, Es, Fr & De
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Based on Collman et al.'s best-selling classic book, Principles and Applications of Organotransition Metal Chemistry, Hartwig's text consists of new or thoroughly updated and restructured chapters and provides an in-depth view into mechanism, reaction scope, and applications. It covers the most important developments in the field over the last twenty years with great clarity with a selective, but thorough and authoritative coverage of the fundamentals of organometallic chemistry, the elementary reactions of these complexes, and many catalytic processes occurring through organometallic intermediates, making this the Organotransition Metal Chemistry text for a new generation of scientists.

Organotransition Metal Chemistry: Applications to Organic Synthesis

Organotransition Metal Chemistry: Applications to Organic Synthesis
Applications to Organic Synthesis

by S. G. Davies

  • Publisher : Elsevier
  • Release : 2013-10-22
  • Pages : 430
  • ISBN : 1483285847
  • Language : En, Es, Fr & De
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Although organotransition metal chemistry has been developing rapidly over the past 20 years, it is only recently that applications of transition metal complexes to organic synthesis have started to be exploited. This unique book provides an introduction to organometallic chemistry for chemists who have little or no experience in the field, describes the work that has already been done using organotransition metal complexes for synthesis, and indicates to organic and organometallic chemists the type of synthetic problems that can be solved using organometallic compounds. It covers all major advances that have been made in this rapidly expanding area of chemistry, including not only reactions that already have well established applications for synthesis but also many recently discovered potentially useful reactions, providing a survey of recent literature.

Organotransition Metals in Organic Synthesis

Organotransition Metals in Organic Synthesis
Fundamentals and Applications

by Sugata Chatterjee

  • Publisher : Elsevier
  • Release : 2020-12-15
  • Pages : 315
  • ISBN : 9780128184776
  • Language : En, Es, Fr & De
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Organotransition Metals in Organic Synthesis: Fundamentals and Applications provides a fundamental understanding on how to use transition and main group metals to synthesize simple and complex molecules with a high degree of selectivity. This book details the basic concepts, elementary reactions, and latest developments of organometallic chemistry surrounding the transition metals. Topics covered include electronic configuration and structural, methods for carbon-transition metal bond creation, cleavage of metal-carbon bonds to form new carbon-carbon bonds, chemo-, region-, stereo- and enantio- control, and heterogeneous organometallic reactions. This book is an ideal resource for researchers and students working with metals in organic synthesis and organometallic chemistry, including those having no prior exposure to organometallic chemistry in synthesis. Includes extensive coverage of methods for creating carbon-transition metal bonds, such as oxidative addition, oxidative coupling, hydro and carbometallation, carbonyl insertion, transmetallation and metal carbenes and metathesis Ideal for students and researchers new to the pharmaceutical industry or organometallic chemistry in general, covering foundational information as well as select advanced applications Covers metals in organic synthesis, unprecedented selectivity, clean reactions, mild conditions, high yields, along with improvisation methods for existing synthesis methods

Organotransition-Metal Chemistry

Organotransition-Metal Chemistry
A Book

by Yoshio Ishii

  • Publisher : Springer
  • Release : 2012-03-19
  • Pages : 398
  • ISBN : 9781468421446
  • Language : En, Es, Fr & De
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In every generation the achievements in science have served mankind. The progress accomplished by one generation stimulates the next generation to even greater achievements, which may take the form of increasing, crystallizing, or detailing existing theo ries. Other forms, generally resulting from persistence and enlight ened fortune, open new areas of investigation previously unimagined and have an impact that may be felt for many years. An example of this latter form of achievement was the prepara tion and elucidation of the structures of dicyclopentadienyliron (ferrocene, reported in 1951) dibenzenechromium iodide, triphenyl chromium tristetrahydrofuranate, and numerous olefin-metal ~-com plexes which provided an introduction to new types of chemical bonds the sigma carbon-transition metal bond and the metal ~-complex bond. Initial progress in the field of organotransition-metal chemis try followed the lines of interest generated separately by organic and inorganic chemistry. However, it is becoming increasingly clear that organotransit10n-metal chemistry is not only bridging these two fields, but also crosslinking many other fields of science.

New Pathways for Organic Synthesis

New Pathways for Organic Synthesis
Practical Applications of Transition Metals

by H.M. Colquhoun,J. Holton,D.J. Thompson,M.V. Twigg

  • Publisher : Springer Science & Business Media
  • Release : 2012-12-06
  • Pages : 468
  • ISBN : 1461326516
  • Language : En, Es, Fr & De
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The continually growing contribution of transition metal chemistry to synthetic organic chemistry is, of course, widely recognized. Equally well known is the difficulty in keeping up-to-date with the multifarious reactions and procedures that seem to be spawned at an ever-increasing rate. These can certainly be summarized on the basis of reviews under the headings of the individual transition metals. More useful to the bench organic chemist, however, would be the opposite type of concordance based on the structural type of the desired synthetic product. This is the approach taken in the present monograph, which presents for each structural entity a conspectus of the transition metal-mediated processes that can be employed in its production. The resulting comparative survey should be a great help in devising the optimum synthetic approach for a particular goal. It is presented from an essentially practical viewpoint, with detailed direc tions interspersed in the Houben-Weyl style. The wide scope of the volume should certainly encourage synthetic organic chemists to utilize fully the range and versatility of these transition metal-mediated processes. This will certainly be a well-thumbed reference book! R. A. RAPHAEL Cambridge University v Preface In recent years an enormous amount of work has been done on the catalysis of organic reactions by various transition metal species and on the organic reactivity of organo-transition-metal compounds.

Organotransition Metal Chemistry

Organotransition Metal Chemistry
Fundamental Concepts and Applications

by Akio Yamamoto

  • Publisher : Wiley-Interscience
  • Release : 1986
  • Pages : 455
  • ISBN : 9876543210XXX
  • Language : En, Es, Fr & De
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A systematic, readable treatment of organotransition metal chemistry that provides students, teachers, and practicing chemists with an understanding of basic concepts in catalysis and synthetic procedures using transition metal reagents. Covers basic principles of coordination chemistry, organometallic compounds of transition metals and non-transition metals, reactions, industrial applications, use in synthesis, methods of manipulation for air-sensitive compounds, and an overview of related topics. Well illustrated with figures and formulae.

Principles and Applications of Organotransition Metal Chemistry

Principles and Applications of Organotransition Metal Chemistry
A Book

by James Paddock Collman,Louis S. Hegedus,Jack R. Norton,Richard G. Finke

  • Publisher : Univ Science Books
  • Release : 1987
  • Pages : 989
  • ISBN : 9876543210XXX
  • Language : En, Es, Fr & De
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This textbook introduces students and experienced chemists to a rapidly growing interdisciplinary subject. It incorporates a thorough revision of the earlier edition, and includes all new developments.

Transition Metal Reagents and Catalysts

Transition Metal Reagents and Catalysts
Innovations in Organic Synthesis

by Jiro Tsuji

  • Publisher : John Wiley & Sons
  • Release : 2002-08-16
  • Pages : 496
  • ISBN : 9780471560272
  • Language : En, Es, Fr & De
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Transition Metal Reagents and Catalysts Innovations in Organic Synthesis Jiro Tsuji Emeritus Professor, Tokyo Institute of Technology, Japan Numerous innovative and practical synthetic methods using transition metal complexes as either catalysts or reagents have been developed over the last 35 years. Transition Metal Reagents and Catalysts combines the varied applications of transition metal complexes in a unique and timely book in this rapidly advancing area of organic synthesis. This text is an easily understandable and enjoyable read for organic chemists who are not yet familiar with organo-transition metal chemistry. Transition Metal Reagents and Catalysts presents: * Complete coverage of nearly 35 years of transition metal complex chemistry * An in-depth treatment of many innovative synthetic methodologies * A rational classification of all reactions according to substrates and reaction mechanisms * Examples of important applications of transition metal catalysed reactions. A knowledge of organic synthesis using transition metal complexes is a must for all synthetic organic chemists. Written for chemists who wish to apply novel synthetic methods using transition metal complexes to solve problems in organic and pharmaceutical chemistry, such as synthesis of fine and bulk chemicals and natural products, Transition Metal Reagents and Catalysts is an essential reference source and an indispensible research companion.

Transition Metals in the Synthesis of Complex Organic Molecules

Transition Metals in the Synthesis of Complex Organic Molecules
A Book

by Louis S. Hegedus

  • Publisher : University Science Books
  • Release : 1999
  • Pages : 337
  • ISBN : 9781891389047
  • Language : En, Es, Fr & De
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This second edition offers easy access to the field of organotransition metal chemistry. The book covers the basics of transition metal chemistry, giving a practical introduction to organotransition reaction mechanisms.

Landmarks in Organo-Transition Metal Chemistry

Landmarks in Organo-Transition Metal Chemistry
A Personal View

by Helmut Werner

  • Publisher : Springer Science & Business Media
  • Release : 2008-12-16
  • Pages : 348
  • ISBN : 0387098488
  • Language : En, Es, Fr & De
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Since the discovery of ferrocene and the sandwich-type complexes, the development of organometallic chemistry took its course like an avalanche and became one of the scientific success stories of the second half of the twentieth century. Based on this development, the traditional boundaries between inorganic and organic chemistry gradually disappeared and a rebirth of the nowadays highly important field of homogeneous catalysis occurred. It is fair to say that despite the fact that the key discovery, which sparked it all off, was made more than 50 years ago, organometallic chemistry remains a young and lively discipline.

Organotransition Metal Chemistry

Organotransition Metal Chemistry
A Book

by Anthony F. Hill,A. Hill

  • Publisher : Royal Society of Chemistry
  • Release : 2002
  • Pages : 185
  • ISBN : 9780854046225
  • Language : En, Es, Fr & De
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This book aims to introduce undergraduates to the utility of organotransition metal chemistry, a discipline of importance to scientists in a variety of industry sectors.

Asymmetric Induction in Organo-transition Metal Complexes

Asymmetric Induction in Organo-transition Metal Complexes
Applications to Organic Synthesis

by Brian Arthur Roden

  • Publisher : Unknown Publisher
  • Release : 1989
  • Pages : 508
  • ISBN : 9876543210XXX
  • Language : En, Es, Fr & De
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Organotransition Metal Chemistry A Mechanistic Approach

Organotransition Metal Chemistry A Mechanistic Approach
A Book

by Richard Heck

  • Publisher : Elsevier
  • Release : 2012-12-02
  • Pages : 350
  • ISBN : 0323154700
  • Language : En, Es, Fr & De
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Organotransition Metal Chemistry: A Mechanistic Approach describes a mechanistic approach to the study of the chemistry of organotransition metals. Organotransition metals are discussed in relation to their reactions with specific functional groups or types of compounds rather than by metals. Topics covered include the formation of hydrogen and carbon bonds to transition metals; reactions of transition metal δ- and π-bonded derivatives; and addition and elimination reactions of olefinic compounds. This book is comprised of 10 chapters and begins with a historical overview of organotransition metal chemistry, together with the unique chemistry of transition metals and mechanisms of ligand replacements. The following chapters discuss the methods of preparation of hydrido complexes and carbon-transition metal bonds; homogeneous hydrogenation reactions; isomerization, dimerization, oligomerization, and polymerization of olefins; and reactions of dienes, trienes, and tetraenes with transition metal compounds. Transition metal reactions with acetylenes and carbon monoxide as well as organic carbonyl compounds are also examined. This monograph should be of value to organic chemists as well as students and researchers of organic chemistry.

Applications of Organo-transition Metal Complexes in Organic Synthesis

Applications of Organo-transition Metal Complexes in Organic Synthesis
EUCHEM Conference

by Anonim

  • Publisher : Unknown Publisher
  • Release : 1986*
  • Pages : 83
  • ISBN : 9876543210XXX
  • Language : En, Es, Fr & De
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Organo-Transition Metal Compounds and Related Aspects of Homogeneous Catalysis

Organo-Transition Metal Compounds and Related Aspects of Homogeneous Catalysis
Pergamon Texts in Inorganic Chemistry

by B. L. Shaw,N. I. Tucker

  • Publisher : Elsevier
  • Release : 2013-10-22
  • Pages : 228
  • ISBN : 1483159698
  • Language : En, Es, Fr & De
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Organo-Transition Metal Compounds and Related Aspects of Homogeneous Catalysis deals with the chemistry of organo-transition metal complexes and their uses as homogeneous catalysts and as intermediates in organic synthesis. The compounds are classified mainly from the number of carbon atoms that are actually bonded to the metal and to each other. This volume is comprised of eight chapters and begins with a discussion on alkyls, aryls, acetylides, fluorocarbon complexes, and carbides, along with olefin, allene, and acetylene complexes. The reader is then introduced to π-allylic and related complexes such as fluoroallyl complexes; complexes with conjugated diolefins including fluorodiolefins but excluding cyclobutadienes; cyclopentadienyl-metal, pentadienyl-metal, and related complexes; and arene complexes, related complexes with conjugated trienes, and thiophene complexes such as benzenoid-metal or arene-metal complexes, cyclopheptatriene complexes, and complexes with other six electron donors. Cycloheptatrienyl or tropylium complexes are also considered, along with cyclo-octatetraene, azulene complexes, and carborane complexes. This book will be a valuable source of information for inorganic chemists.

Handbook of Organopalladium Chemistry for Organic Synthesis, 2 Volume Set

Handbook of Organopalladium Chemistry for Organic Synthesis, 2 Volume Set
A Book

by Ei-ichi Negishi

  • Publisher : John Wiley & Sons
  • Release : 2003-11-24
  • Pages : 3424
  • ISBN : 0471473812
  • Language : En, Es, Fr & De
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Organotransition-Metal Chemistry

Organotransition-Metal Chemistry
A Book

by Yoshio Ishii,Minoru Tsutsui

  • Publisher : Springer
  • Release : 1975
  • Pages : 398
  • ISBN : 9876543210XXX
  • Language : En, Es, Fr & De
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Organic Synthesis Highlights

Organic Synthesis Highlights
A Book

by Hans-Josef Altenbach,Hans-Ulrich Reißig,Karsten Krohn,Manfred Braun,Johann Mulzer

  • Publisher : John Wiley & Sons
  • Release : 2008-11-20
  • Pages : 422
  • ISBN : 3527621393
  • Language : En, Es, Fr & De
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This unusual collection of 49 essays gives an overview of the trends and accomplishments of synthetic organic chemistry in recent years. Unique in its approach, it deals with almost every aspect of modern synthesis. The first part of the book describes methods and reagents, with particular emphasis on rapidly developing organometallic and biooriented procedures. In the second part, these tools are applied to the syntheses of interesting target compounds and natural compounds with remarkable physiological properties. Mechanistic discussions and retrosynthetic analyses are included. More than 1000 up-to-date references help the reader to pursue the topics highlighted here. This book gives both the active researcher and the advanced student insight into the competitive atmosphere, creativity, and resourcefulness so characteristic of organic synthesis today.

Organic Synthesis via Organometallics (OSM 4)

Organic Synthesis via Organometallics (OSM 4)
Proceedings of the Fourth Symposium in Aachen, July 15 to 18, 1992

by Dieter Enders

  • Publisher : Vieweg + Teubner Verlag
  • Release : 1993
  • Pages : 223
  • ISBN : 9876543210XXX
  • Language : En, Es, Fr & De
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Organometallics playa key role in organic synthesis. Carbon carbon bond formation without main group and transition metal based reagents as well as catalysts is hardly imaginable, and the tremendous success in recent years in the field of stereoselective synthesis of complex biologically active com­ pounds would have been impossible without the advances in organometallic chemistry. From the wealth of carbon carbon bond forming reactions in organotransition metal chemistry many new methods have evolved. This was aided considerably by a deepening of our understanding of the relevant reaction mechanisms. Organometallic chemistry is the bridge par excellence between the traditional fields of inorganic and organiC chemistry. It was the intention of the "Volkswagen-Stiftung" to broaden this bridge by starting in 1986 the new interdisciplinary program "Organic Synthesis via Organo­ metallics". From its very beginning this program grew up after 6 years to now more than 60 projects and its encompasses besides its main topic "Organic Synthesis" mechanistic and structural aspects of organometallic chemistry as well. In a series of symposia sponsored by the "Volkswagen-Stiftung", the former of which were held in Hamburg (February 1986), Wiirzburg (October 1988) and Marburg (July 1990), a forum for intensive discussions and SCientific exchange was established. There, scientists participating in the program met with other experts form academia and from industry. The forth symposium was held in Aachen from July 15 to 18, 1992.

The Organometallic Chemistry of the Transition Metals

The Organometallic Chemistry of the Transition Metals
A Book

by Robert H. Crabtree

  • Publisher : John Wiley & Sons
  • Release : 2009-04-06
  • Pages : 520
  • ISBN : 0470257628
  • Language : En, Es, Fr & De
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"One impressive and compressive book. . . . This review would have to be book size to do full justice to all the insights in this volume." —Journal of Metals Online Fully updated and expanded to reflect recent advances, this Fifth Edition of the classic text provides students and professional chemists with a comprehensive introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and?detailed descriptions of contemporary applications. With increased focus on organic synthesis applications, nanoparticle science, and green chemistry, the Fifth Edition brings this vital resource up to date. New to the Fifth Edition: Chapters have been updated with relevant examples in the field, modern trends, and new applications; the organic applications chapter has been completely rewritten New end-of-chapter problems, along with their solutions Coverage enhanced with developments in nanoparticle science Increased focus on green chemistry An unparalleled pedagogic resource as well as a valuable working reference for professional chemists, with comprehensive coverage and up-to-date information, students and researchers?in organic and organometallic chemistry will turn to The Organometallic Chemistry of the Transition Metals, Fifth Edition for the critical information they need on organometallic compounds, their preparation, and their use in synthesis.