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Pincer Compounds

Pincer Compounds
Chemistry and Applications

by David Morales-Morales

  • Publisher : Elsevier
  • Release : 2018-04-11
  • Pages : 754
  • ISBN : 0128129328
  • Language : En, Es, Fr & De
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Pincer Compounds: Chemistry and Applications offers valuable state-of-the-art coverage highlighting highly active areas of research—from mechanistic work to synthesis and characterization. The book focuses on small molecule activation chemistry (particularly H2 and hydrogenation), earth abundant metals (such as Fe), actinides, carbene-pincers, chiral catalysis, and alternative solvent usage. The book covers the current state of the field, featuring chapters from renowned contributors, covering four continents and ranging from still-active pioneers to new names emerging as creative strong contributors to this fascinating and promising area. Over a decade since the publication of Morales-Morales and Jensen’s The Chemistry of Pincer Compounds (Elsevier 2007), research in this unique area has flourished, finding a plethora of applications in almost every single branch of chemistry—from their traditional application as very robust and active catalysts all the way to potential biological and pharmaceutical applications. Describes the chemistry and applications of this important class of organometallic and coordination compounds Includes contributions from global leaders in the field, featuring pioneers in the area as well as emerging experts conducting exciting research on pincer complexes Highlights areas of promising and active research, including small molecule activation, earth abundant metals, and actinide chemistry

The Chemistry of Pincer Compounds

The Chemistry of Pincer Compounds
A Book

by David Morales-Morales,Craig G.M. Jensen

  • Publisher : Elsevier
  • Release : 2011-08-11
  • Pages : 466
  • ISBN : 9780080545158
  • Language : En, Es, Fr & De
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Pincer complexes are formed by the binding of a chemical structure to a metal atom with at least one carbon-metal bond. Usually the metal atom has three bonds to a chemical backbone, enclosing the atom like a pincer. The resulting structure protects the metal atom and gives it unique properties. The last decade has witnessed the continuous growth in the development of pincer complexes. These species have passed from being curiosity compounds to chemical chameleons able to perform a wide variety of applications. Their unique metal bound structures provide some of the most active catalysts yet known for organic transformations involving the activation of bonds. The Chemistry of Pincer Compounds details use of pincer compounds including homogeneous catalysis, enantioselective organic transformations, the activation of strong bonds, the biological importance of pincer compounds as potential therapeutic or pharmaceutical agents, dendrimeric and supported materials. * Describes the chemistry and applications of this important class of organometallic and coordination compounds * Covers the areas in which pincer complexes have had an impact * Includes information on more recent and interesting pincer compounds not just those that are well-known

Advances in Organometallic Chemistry

Advances in Organometallic Chemistry
A Book

by Pedro J. Perez

  • Publisher : Academic Press
  • Release : 2020-03-03
  • Pages : 314
  • ISBN : 0128206918
  • Language : En, Es, Fr & De
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Advances in Organometallic Chemistry, Volume 73, the latest release in this longstanding serial, is known for its comprehensive coverage of topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more. It is ideal for a wide range of researchers involved in organometallic chemistry, including synthetic protocols, mechanistic studies and practical applications. Specific chapters in this new release include Metal carbonyl promoted multicomponent coupling of alkyne for synthesis of heterocyclic compounds, Group 10 metal(0) complexes stabilized by phosphorus and carbon donor ligands, Synthesis of Nitrogen-containing Molecules via Transition Metal-Catalyzed Reactions on Isoxazoles, Anthraniils and Benzoisoxazoles, and more. Contains contributions from leading authorities in the field of organometallic chemistry Covers topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more Informs and updates readers on the latest developments in the field Carefully edited to provide easy-to-read material

The Privileged Pincer-Metal Platform: Coordination Chemistry & Applications

The Privileged Pincer-Metal Platform: Coordination Chemistry & Applications
A Book

by Gerard van Koten,Robert A Gossage

  • Publisher : Springer
  • Release : 2015-08-27
  • Pages : 374
  • ISBN : 3319229273
  • Language : En, Es, Fr & De
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The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.

Pincer-Metal Complexes

Pincer-Metal Complexes
Applications in Catalytic Dehydrogenation Chemistry

by Akshai Kumar

  • Publisher : Elsevier
  • Release : 2021-11-12
  • Pages : 244
  • ISBN : 0128220929
  • Language : En, Es, Fr & De
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Pincer-Metal Complexes: Applications in Catalytic Dehydrogenation Chemistry provides an overview of pincer-metal catalytic systems that transform hydrocarbons and their derivatives from an synthetic and mechanistic point-of-view. This book provides thorough coverage of the operating mechanisms and dehydrogenation catalyst compatibility in both functionalized and unfunctionalized hydrocarbon systems. In addition, it includes success stories of pincer-metal systems, as well as current and future challenges. The book is an ideal reference for researchers practicing synthetic organic chemistry, inorganic chemistry, organometallic chemistry and catalysis in academia and industry. In recent years there has been a surge in the research on hydrocarbon dehydrogenation catalytic systems that are compatible with polar substituents. This helps facilitate formulation of tandem processes that are not limited to hydrocarbon transformation but also to hydrocarbon functionalization in a single pot. Covers applications of pincer-metal complexes in organic transformations Includes pincer-group 8 and 9 metal complexes for alkane dehydrogenations Features a discussion of pincer-metal complexes for the dehydrogenation of functionalized hydrocarbons and electro-catalytic transformations

Advances in Organometallic Chemistry

Advances in Organometallic Chemistry
A Book

by Pedro J. Perez

  • Publisher : Academic Press
  • Release : 2021-06-17
  • Pages : 270
  • ISBN : 0323850693
  • Language : En, Es, Fr & De
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Advances in Organometallic Chemistry, Volume 76, the latest release in this longstanding serial is known for its comprehensive coverage of topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more. It is ideal for a wide range of researchers involved in organometallic chemistry, including synthetic protocols, mechanistic studies and practical applications. Contains contributions from leading authorities in the field of organometallic chemistry Covers topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more Informs and updates readers on the latest developments in the field Carefully edited to provide easy-to-read material

Cyclometalation Reactions

Cyclometalation Reactions
Five-Membered Ring Products as Universal Reagents

by Iwao Omae

  • Publisher : Springer Science & Business Media
  • Release : 2014-01-23
  • Pages : 208
  • ISBN : 4431546049
  • Language : En, Es, Fr & De
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This book provides a review of cyclometalation reactions and organometallic intramolecular-coordination five-membered ring products, the most active type of reactions in synthetic organic reactions and their products. Included is the discovery of intramolecular-coordination bonds in cyclometalation reactions and the characteristics of those reactions, as well as the reasons that their five-membered ring compounds are very easily synthesized through such reactions. In addition, the applications of cyclometalation reactions and five-membered ring products, synthetic applications, catalysts, and other products are described. These topics are of special interest for industrial researchers.

PCP Pincer Compounds

PCP Pincer Compounds
Synthesis and Application as Methanol Carbonylation Catalysts

by Timothy James Reynolds

  • Publisher : Unknown Publisher
  • Release : 2012
  • Pages : 314
  • ISBN : 9876543210XXX
  • Language : En, Es, Fr & De
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Organic Materials as Smart Nanocarriers for Drug Delivery

Organic Materials as Smart Nanocarriers for Drug Delivery
A Book

by Alexandru Mihai Grumezescu

  • Publisher : William Andrew
  • Release : 2018-03-26
  • Pages : 768
  • ISBN : 0128136642
  • Language : En, Es, Fr & De
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Organic Materials as Smart Nanocarriers for Drug Delivery presents the latest developments in the area of organic frameworks used in pharmaceutical nanotechnology. An up-to-date overview of organic smart nanocarriers is explored, along with the different types of nanocarriers, including polymeric micelles, cyclodextrins, hydrogels, lipid nanoparticles and nanoemlusions. Written by a diverse range of international academics, this book is a valuable reference for researchers in biomaterials, the pharmaceutical industry, and those who want to learn more about the current applications of organic smart nanocarriers. Explores the most recent molecular- and structure-based applications of organic smart nanocarriers in drug delivery Highlights different smart nanocarriers and assesses their intricate organic structural properties for improving drug delivery Assesses how molecular organic frameworks lead to more effective drug delivery systems

Metal-Ligand Co-operativity

Metal-Ligand Co-operativity
Catalysis and the Pincer-Metal Platform

by Gerard van Koten,Karl Kirchner,Marc-Etienne Moret

  • Publisher : Springer Nature
  • Release : 2021
  • Pages : 451
  • ISBN : 3030689166
  • Language : En, Es, Fr & De
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This book provides researchers in the fields of organic chemistry, organometallic chemistry and homogeneous catalysis with an overview of significant recent developments in the area of metal-ligand cooperativity, with a focus on pincer architectures. The various contributions highlight the widespread impact of M-L co-operativity phenomena on modern organometallic chemistry and catalyst development. The development of efficient and selective catalytic transformations relies on the understanding and fine control of the various elementary reactions that constitutes a catalytic cycle. Co-operative ligands, which actively participate in bond making and bond breaking together to the metal they support, open up new avenues in this area. In particular, buttressing a weak or reactive metal-ligand bond by flanking coordinating arms in a pincer ligand design is proving a versatile strategy to access robust metal complexes that exhibit unusual and selective reactivity patterns.

Pincer and Pincer-Type Complexes

Pincer and Pincer-Type Complexes
Applications in Organic Synthesis and Catalysis

by Kálmán J. Szabó,Ola F. Wendt

  • Publisher : John Wiley & Sons
  • Release : 2014-06-10
  • Pages : 320
  • ISBN : 3527681337
  • Language : En, Es, Fr & De
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This new book on this hot topic summarizes the key achievements for the synthesis and catalytic applications of pincer and pincer-type complexes, providing readers with the latest research highlights. The editors have assembled an international team of leaders in the field, and their contributions focus on the application of various pincer complexes in modern organic synthesis and catalysis, such as C-C and C-X bond forming reactions, C-H bond functionalization, and the activation of small molecules, as well as asymmetric catalysis. A must-have for every synthetic chemist in both academia and industry intending to develop new catalysts and improved synthetic protocols.

Modern Carbonylation Methods

Modern Carbonylation Methods
A Book

by László Kollár

  • Publisher : John Wiley & Sons
  • Release : 2008-06-25
  • Pages : 383
  • ISBN : 3527621555
  • Language : En, Es, Fr & De
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Comprehensively covering modern carbonylation chemistry, this book is an indispensable companion for all synthetic chemists working in industry and academia. This monograph contains everything there is to know from recent advances in the investigation of carbonylation catalysts, via coordination chemistry to the synthetic application of transition metal catalyzed carbonylations.

Alkane Functionalization

Alkane Functionalization
A Book

by Armando J. L. Pombeiro,Maria de Fatima Costa Guedes da Silva

  • Publisher : Wiley
  • Release : 2019-02-11
  • Pages : 648
  • ISBN : 111937880X
  • Language : En, Es, Fr & De
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Presents state-of-the-art information concerning the syntheses of valuable functionalized organic compounds from alkanes, with a focus on simple, mild, and green catalytic processes Alkane Functionalization offers a comprehensive review of the state-of-the-art of catalytic functionalization of alkanes under mild and green conditions. Written by a team of leading experts on the topic, the book examines the latest research developments in the synthesis of valuable functionalized organic compounds from alkanes. The authors describe the various modes of interaction of alkanes with metal centres and examine theoxidative alkane functionalization upon C-O bond formation. They address the many types of mechanisms, discuss typical catalytic systems and highlight the strategies inspired by biological catalytic systems. The book also describes alkane functionalization upon C-heteroatom bond formation as well as oxidative and non-oxidative approaches. In addition, the book explores non-transition metal catalysts and metal-free catalytic systems and presents selected types of functionalization of sp3 C-H bonds pertaining to substrates other than alkanes. This important resource: Presents a guide to the most recent advances concerning the syntheses of valuable functionalized organic compounds from alkanes Contains information from leading experts on the topic Offers information on the catalytic functionalization of alkanes that allows for improved simplicity and sustainability compared to current multi-stage industrial processes Explores the challenges inherent with the application of alkanes as starting materials for syntheses of added value functionalized organic compounds Written for academic researchers and industrial scientists working in the fields of coordination chemistry, organometallic chemistry, catalysis, organic synthesis and green chemistry, Alkane Functionalization is an important resource for accessing the most up-to-date information available in the field of catalytic functionalization of alkanes.

The Chemistry of Organomagnesium Compounds, 2 Volume Set

The Chemistry of Organomagnesium Compounds, 2 Volume Set
A Book

by Zvi Rappoport,Ilan Marek

  • Publisher : John Wiley & Sons
  • Release : 2008-04-30
  • Pages : 920
  • ISBN : 047075186X
  • Language : En, Es, Fr & De
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Magnesium remains almost unique among the metals in its ability to react directly with a wide variety of compounds. This organic chemistry field has seen steady progress, and a volume on this topic is long overdue. In the tradition of the Patai Series this title treats all aspects of functional groups, containing chapters on the theoretical and computational foundations; on analytical and spectroscopic aspects with dedicated chapters on Mass Spectrometry, NMR, IR/UV, etc.; on reaction mechanisms; on applications in syntheses. Depending on the functional group there are also chapters on industrial use, on effects in biological and/or environmental systems. Since the area of Organomagnesium Chemistry continues to grow far beyond the classical Grignard Reagents, this is an essential resource to help the reader keep abreast of the latest developments.

Applied Homogeneous Catalysis with Organometallic Compounds

Applied Homogeneous Catalysis with Organometallic Compounds
A Comprehensive Handbook in Four Volumes

by Boy Cornils,Wolfgang A. Herrmann,Matthias Beller,Rocco Paciello

  • Publisher : John Wiley & Sons
  • Release : 2017-09-05
  • Pages : 1872
  • ISBN : 3527651756
  • Language : En, Es, Fr & De
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The completely revised third edition of this four-volume classic is fully updated and now includes such topics as as CH-activation and multicomponent reactions. It describes the most important reaction types, new methods and recent developments in catalysis. The internationally renowned editors and a plethora of international authors (including Nobel laureate R. Noyori) guarantee high quality content throughout the book. A "must read" for everyone in academia and industry working in this field.

Iridium Complexes in Organic Synthesis

Iridium Complexes in Organic Synthesis
A Book

by Luis A. Oro,Carmen Claver

  • Publisher : John Wiley & Sons
  • Release : 2008-12-03
  • Pages : 424
  • ISBN : 3527623086
  • Language : En, Es, Fr & De
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Ranging from hydrogenation to hydroamination, cycloadditions and nanoparticles, this first handbook to comprehensively cover the topic of iridium in synthesis discusses the important advances in iridium-catalyzed reactions, namely the use of iridium complexes in enantioselective catalysis. A must for organic, complex and catalytic chemists, as well as those working with/on organometallics.

Palladacycles

Palladacycles
Synthesis, Characterization and Applications

by Jairton Dupont,Michel Pfeffer

  • Publisher : John Wiley & Sons
  • Release : 2008-09-08
  • Pages : 431
  • ISBN : 3527623221
  • Language : En, Es, Fr & De
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From synthesis to applications in catalysis, material science and biology this much-needed book is the first to comprehensively present everything you need to know about palladacycles. Renowned international authors guarantee high-quality content, making this a must-have for everyone working in the field.

Manganese Catalysis in Organic Synthesis

Manganese Catalysis in Organic Synthesis
A Book

by Jean-Baptiste Sortais

  • Publisher : John Wiley & Sons
  • Release : 2021-08-31
  • Pages : 368
  • ISBN : 3527826114
  • Language : En, Es, Fr & De
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This unique book highlights the most important reactions in the presence of homogeneous manganese catalysts, e.g. reduction reactions, C-H functionalization, cross-coupling reactions etc.

Advances in Bioorganometallic Chemistry

Advances in Bioorganometallic Chemistry
A Book

by Toshikazu Hirao,Toshiyuki Moriuchi

  • Publisher : Elsevier
  • Release : 2018-11-30
  • Pages : 472
  • ISBN : 0128141980
  • Language : En, Es, Fr & De
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Advances in Bioorganometallic Chemistry examines the synthesis, structure and reactivity of bioorganometallics, their pharmaceutical applications, hydrogenase, vitamin B12-like systems, and metalloproteins. It is written by the top researchers in the field and compiled by editors Toshikazu Hirao and Toshiyuki Moriuchi. Developments in this new field of bioorganometallic chemistry, a hybrid between biology and organometallic chemistry, happen very quickly and this comprehensive reference offers the latest research and findings in the field. The book features a discussion of the synthesis, structure, and reactivity of bioorganometallics, and an examination of hydrogenase-like systems, which were designed to demonstrate catalytic activities and functional properties. Advances in Bioorganometallic Chemistry also includes a discussion of bioorganometallics as they relate to medicinal chemistry, specifically applications of metalloproteins, metalloenzymes, and applications in bioimaging. The book concludes with coverage of vitamin B12-like systems, including the latest developments in derivatives designed to perform bio-inspired catalytic reactions. This work is a valuable resource for chemists working in organometallic chemistry and biology, including biochemists, bioorganic chemists, bioinorganic chemists, as well as pharmaceutical scientists, medicinal chemists, and students studying in these areas. Representative authors: R. H. Fish, T. Moriuchi, T. Hirao, H.-B. Kraatz, H. Takaya, T. P. Curran, G. van Koten. E. Rosenberg, J. M. Lynam, C. G. Hartinger, U. Schatzschneider, G. S. Smith, R. Alberto, S. Takenaka, T. Ihara, T. Hayashi, T. Ueno, P. Schollhammer, Y. Shomura, Y. Hisaeda, H. Shimakoshi, B. Kräutler Provides a balanced overview of the latest research in the field of bioorganometallic chemistry, drawing together the top researchers from around the world Covers topics in the areas of synthesis, reactivity, hydrogenase-like systems, medicinal chemistry, applications of metalloproteins, metalloenzymes, and applications in bioimaging

Iridium Catalysts for Organic Reactions

Iridium Catalysts for Organic Reactions
A Book

by Luis A. Oro,Carmen Claver

  • Publisher : Springer Nature
  • Release : 2021-03-29
  • Pages : 457
  • ISBN : 3030690830
  • Language : En, Es, Fr & De
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This new volume “Iridium Catalysts for Organic Reactions” in the series “Topics in Organometallic Chemistry” intends to update several representative well-known reactions and to introduce other less known or new reactions in particular covering sustainability aspects. Iridium complexes are efficient in many catalytic homogeneous transformations providing high efficiency in both results, activity and selectivity. The interest of the book lies in the presentation of the advances, new perspectives and application in a variety of representative iridium-catalysed reaction. All chapters in the volume are contributed by relevant international experts in the field. The book is aimed at researchers, graduate students and synthetic chemists at all levels in academia and industry.